Ozone vs PM2.5: easily understand the difference

In summary: Ozone and fine particulate matter (PM2.5) represent two major forms of urban pollution with distinct origins and effects. Ozone, a gas formed by a chemical reaction between sunlight and vehicle emissions, reaches its peak in summer and irritates the respiratory tract. PM2.5, produced by combustion (traffic, heating, industry), persists year-round and penetrates deep into the lungs and blood, increasing cardiovascular risks.
To protect yourself, the R-PUR mask , thanks to its multi-layer FFP3+ filtration down to PM0.05 , captures ultrafine particles and neutralizes toxic gases like ozone, offering an effective, comfortable and durable solution for breathing healthier air in the city.

  1. Breathing in the city: understanding the difference between ozone and PM2.5

  2. Gases vs particles: what are ozone and PM2.5 ?

  3. Distinct origins: how are these pollutants formed ?

  4. Distinct impacts on health

Breathing in the city: understanding the difference between ozone and PM2.5

Urban air quality has become a major concern for city dwellers worried about their health and a sustainable lifestyle. Among the many pollutants, two dominate discussions: ozone and PM2.5 .
Although they both threaten respiratory health, they differ profoundly in their composition, origin, and effects.
The smog you see isn't a single substance, but a mixture of invisible threats. Let's clarify these two forms of pollution to better navigate the challenges of urban air quality.

Ozone , a colorless gas (O₃), forms when sunlight reacts with vehicle emissions and industrial pollutants such as nitrogen oxides (NOx) and volatile organic compounds (VOCs). It can be considered the "bad guy of summer"—its levels rise during heat waves.
In contrast, PM2.5 refers to microscopic particles (≤2.5 microns) originating from forest fires, construction dust, or diesel engines. These particles persist year-round, sometimes appearing as a grey haze.

Why is this distinction important? Ozone acts as a direct respiratory irritant, inflaming the airways and worsening asthma. PM2.5, on the other hand, penetrates deeper, lodging in the lungs and passing into the bloodstream, causing cardiovascular problems.
Although both pollutants degrade air quality, their mechanisms and therefore their solutions differ. Let's see how to protect your health in cities where these invisible adversaries thrive.

Nuclear power plant with smoke, a sunrise in the background.

Gases vs particles: what are ozone and PM2.5?

Ozone: an invisible gaseous pollutant

Ozone (O₃) has a dual nature — a protective shield in the upper atmosphere, but a harmful gas at ground level.
It forms when NOx from traffic or industry reacts with VOCs under the influence of sunlight. This gaseous pollutant reaches its peak in summer.
Unlike visible smog, ozone is undetectable to our senses, hence the importance of air quality alerts. Its high chemical reactivity causes respiratory irritation, especially during physical exertion when breathing is deeper.

PM2.5: microscopic particles

PM2.5 represents a unique challenge: solid or liquid particles 30 times smaller than a human hair.
They come from direct sources such as forest fires or brake dust, but also from atmospheric chemical reactions between sulfur dioxide (SO₂) and nitrogen oxides (NOx).
Their tiny size allows them to bypass the natural filters of the nose and reach the alveoli of the lungs, and even the bloodstream.
Unlike ozone, PM2.5 levels often increase in winter, when combustion for heating and temperature inversions trap pollution near the ground.

Both pollutants harm air quality, but in different ways:

  • Ozone, an irritant gas, acts chemically on the respiratory tract.

  • PM2.5, physical particles, cause systemic inflammation and cardiovascular stress.

Children, the elderly, and outdoor workers are the most at risk. Understanding this difference allows for better choices regarding protective measures—masks, activity schedules, and actions for cleaner transportation.

Distinct origins: how are these pollutants formed?

Ozone: a chemical reaction powered by the sun

Tropospheric ozone is not directly emitted. It forms when NOx and VOCs react under sunlight.
Cars, power plants, and the use of solvents release these precursors. Nitrogen dioxide (NO₂) decomposes under UV light, releasing atomic oxygen which forms O₃ — a process accelerated by heat.
Thus, heavily congested cities like Los Angeles experience high levels of ozone.
Invisible and often mistaken for "clear" air, ozone is a secondary pollutant that can travel far, reaching rural areas where it damages crops (wheat, soybeans, etc.).

Reducing NOx and VOC emissions is therefore essential, but their summer peaks also illustrate the impact of climate change on air pollution.

PM2.5: a mixture of direct emissions and chemical reactions

PM2.5 has a dual origin:

  • Primary products , resulting directly from combustion (dust, smoke, soot);

  • Secondary , formed in the atmosphere when SO₂, NOx and ammonia react to produce sulfates and nitrates.

These particles do not require sunlight — therefore they are present all year round.
In winter, wood heating increases their concentration; in summer, forest fires cause it to explode.
Their danger lies in their size: they penetrate deep into the body.
For example, agricultural ammonia reacting with urban NOx forms ammonium nitrate, thus linking rural and industrial areas in the same pollution pattern.

Distinct impacts on health

The effects of ozone: direct respiratory irritation

Ozone irritates the throat, causes coughing, and makes breathing painful. It causes inflammation of the bronchi, comparable to a "sunburn" on the lungs.
It aggravates chronic respiratory diseases (asthma, emphysema, bronchitis) and increases the risk of infection.
Outdoor workers, cyclists and athletes are particularly vulnerable during the summer.

The effects of PM2.5: a threat to the lungs and heart

PM2.5 particles, whether solid or liquid, originating from engines, fires or factories, penetrate as far as the pulmonary alveoli and pass into the blood.
They reduce respiratory capacity, cause coughing, shortness of breath, and increase the risk of heart attack, arrhythmia and premature death .
Prolonged exposure leads to chronic inflammation, oxidative stress, and mitochondrial damage.
Children, the elderly, and people with heart conditions are the most affected.

Children vs. adults: different vulnerabilities

Children inhale 20 to 80% more PM2.5 than adults because of their size and breathing rate.
Each 10 μg/m³ increase in PM2.5 increases pediatric emergency room visits by 2.4%.
In adults, ozone peaks are more dangerous: +20 ppb leads to +5% of visits for respiratory distress.
Seniors and outdoor workers remain exposed to both, which calls for targeted public policies.

The R-PUR mask: effective respiratory protection

Designed and manufactured in France, the R-PUR mask represents a new generation of respiratory protection designed for urban environments and activities exposed to fine particles.
It captures even the finest particles down to PM0.05 , which are six times smaller than those stopped by a standard FFP3 mask. This exceptional performance is based on a multi-layered technology combining:

  • a filtration capable of trapping ultrafine particles (PM2.5, PM10, pollen, dust, heavy metals);

  • a layer of activated carbon that neutralizes toxic gases and volatile organic compounds (VOCs) , such as carbon monoxide (CO) , nitrogen dioxide (NO₂) or ozone (O₃) .

Beyond its high efficiency, the R-PUR mask focuses on comfort and ergonomics . Its memory foam ensures a perfect seal without pressure points, while its fastening system guarantees optimal stability, even during prolonged activity.
Its breathable design, optimized exhalation valve and anti-fog treatment make it a choice ally for cyclists, motorcyclists, sport shooters or city dwellers concerned about their health.

By combining technology, comfort and durability , the R-PUR mask stands out as a high-performance solution for breathing cleaner air, even in the most exposed environments.

Discover the R-PUR anti-pollution mask to protect your respiratory system.

Man with an anti-pollution mask on his face.

FAQ

Which pollutant is more concerning: ozone or fine particles (PM2.5)?

Ozone and PM2.5 both affect respiratory health, but their effects differ.
Ozone, a reactive gas, irritates the respiratory tract and aggravates illnesses such as asthma, especially on hot, sunny days.
PM2.5, microscopic particles, penetrate deep into the lungs and can even pass into the blood, increasing cardiovascular and respiratory risks throughout the year.
The World Health Organization (WHO) classifies PM2.5 as a major environmental threat, while ozone remains a significant danger in summer. Protecting ourselves against both ensures a healthier urban life.

What is the difference between PM2.5 and tropospheric ozone?

PM2.5 refers to ultrafine particles (≤2.5 microns) produced by combustion — vehicle engines, forest fires or industrial processes.
Ozone (O₃) is a gas formed when sunlight reacts with pollutants such as NOx and VOCs.
PM2.5 can be seen as an "invisible dust" that we breathe, while ozone is a "summer smog" gas.
Their different nature — solid particles versus reactive gas — influences how they are measured and combated.

Are ozone and fine particles the same thing?

No! Ozone is a gas produced by chemical reactions activated by the sun, while particulate pollution (PM2.5) consists of droplets or solid particles emitted directly or formed in the atmosphere.
Ozone reaches its peaks during heat waves, while PM2.5 persists all year round.
Both are harmful to health, but require different approaches: reducing car emissions for ozone, and air purifiers or filtering masks for PM2.5.

Is ozone a risk to indoor air quality?

Ozone degrades quickly and does not stagnate indoors.
However, outdoor ozone can enter homes and react with household products (air fresheners, cleaners), thus forming new secondary pollutants.
Avoid air purifiers that generate ozone, as they release this gas directly.
For healthier indoor air, prioritize good ventilation and HEPA filters capable of capturing PM2.5 and VOCs.

Is breathing ozone dangerous to health?

Yes. Ozone causes inflammation of the respiratory tract, comparable to a "sunburn" in the lungs, and can trigger asthma attacks or a feeling of shortness of breath.
Children, the elderly, and outdoor athletes should limit their exposure during periods of intense heat.
Air quality apps allow you to track ozone spikes in real time, and wearing masks with ozone-neutralizing filters — such as those made with activated carbon — helps reduce exposure.

homme d'une trentaine d'année sans barbe et cheveux chatains

Alexandre Le Boucher - CEO, R-PUR

As someone who cycles every day, I am exposed to odorless and invisible air pollution. The impact that the R-PUR cycling mask has had on my health means that I will never go back.

LinkedIn profile